Like school shootings, workplace shootings constitute another subcategory of mass shootings. In workplace incidents, the shooter is usually a current or former employee who targets co-workers.
Workplace mass shootings rose to national attention following a string of incidents in the late 1980s to early 90s involving employees of U.S. post offices; the slang term "going postal" had its origins in these incidents.
Wikipedia's entry summarizes some of the major post office incidents.
Selected statistical reports on workplace violence in general.
From the Bureau of Labor Statistics; covers all shootings 1997-2010, not only those with multiple fatalities.
Issued August 2000; also known as the Califano Commission report.
FBI-issued report; no date, but based upon a symposium held in June 2002.